This study explores traditional adhesives using an ethnobiological approach within a multisocioecological context in Zambia. Through semi-structured interviews, videotaped demonstrations, and herbarium collections, we investigated the traditional adhesives people know and use, the flexibility of production processes, resource usage, and knowledge transmission in adhesive production. Our findings reveal flexibility in adhesive production systems. People use a wide range of organic and inorganic materials in their adhesive recipes. Recipes are flexible, demonstrating the ability to adapt to changes and substitute materials as needed to achieve the desired end product. Additionally, our study reveals a variety of redundant pathways for knowledge transmission typically confined within individual population groups. These include same-sex vertical transmission and distinct learning spaces and processes. Also, we identified material procurement zones showing that people are prepared to travel 70 km for ingredients. We use our findings to review the archaeology and we discuss the identification of archaeological adhesives, the functional roles of adhesive materials, adhesive storage, and the sustained human interaction with species from families such as Euphorbiaceae and Apiade. Our findings underscore the diversity and adaptability of traditional adhesive production and suggest that further research on adhesives would reveal similar diversity within the archaeological record.

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Evidence of different compound resin-based adhesives is present in South Africa from at least 77000 years ago. Ancient glue production is considered one of the oldest known highly complex technologies, requiring advanced technological and mental abilities. However, our current knowledge of adhesive materials, recipes, and uses in South Africa is limited by the lack of in-depth analysis and molecular characterization of residues. To deepen our knowledge of past adhesive technology, we performed a detailed multi-analytical analysis (use-wear, XRD, μ-CT, IR spectroscopy, GC-MS) of 30 Later Stone Age tools with adhesive remains from Steenbokfontein Cave, South Africa. At the site, tools made of various rocks were hafted with compound adhesives, and we identified three recipes: 1) resin/tar of Widdringtonia or Podocarpus species combined with hematite; 2) resin/tar of Widdringtonia or Podocarpus species mixed with hematite and another plant exudate; 3) resin/tar without hematite. The studied scrapers were used in hide-working activities, and the studied cutting tools were used to work animal and soft plant matters. All scrapers display evidence of intense resharpening and were discarded when no longer useable. The combination of different methods for residue analysis reveals the flexibility of adhesive technology at Steenbokfontein. Despite the consistent use of conifer resin/tar throughout the sequence, we observed that other ingredients were added or excluded independently of the tools’ raw materials and functions. Our results highlight the long-lasting tradition of using adhesive material from conifer species but also the adaptability and flexibility of adhesive traditions. The systematic application of this multi-analytical approach to Pleistocene adhesives will be useful to better characterise adhesive traditions and enhance the debate on the technological, cognitive, and behavioural implications of this technology.@en

Archaeological findings prove the appearance and use of birch bark tar since the Middle Palaeolithic. The production and use of birch bark tar and pine wood tar has overlapped since at least the late Neolithic, but probably for much longer. The reliable chemical identification of such archaeological tar residues can offer valuable insights into, for example, ancient technical complexity, trade and culture. In this context, the scarcity of these mainly organic residue findings in the archaeological record bears the need for non-destructive analytical tools. However, there is currently no systematic proposed way for this purpose. We aim here to verify the organic nature and test the reliability of the identification of archaeological pine wood tar and birch bark tar with a combination of SEM-EDS, FTIR microspectroscopy in reflectance mode and XRD. We examined a set of experimental adhesive replicas of pine tar and birch tar in pristine form, but also after a three-year-long weathering experiment. Additionally, we studied a set of archaeological samples, consisting of Mesolithic bone/antler points with adhering hafting residues, form the Dutch North Sea. This research shows that degradation negatively influences the reliable verification and identification of the organic residue constituents significantly. SEM-EDS as a starting point of analysis verifies the residue's organic nature, but it cannot be used to identify birch or pine tar. XRD can identify crystalline additives in the adhesive mixture, like ochre and wax, as well as phases related to the artefact's environment of burial and provenance. Micro-FTIR is also capable of verifying the organic matter of the residue constituents. The differentiation of birch and pine tars is hindered by vibrational modes occurring in neighbouring wavenumbers for both tars, and by the limited research on degradation markers indicative of thermal treatment to prove tar production. Until reference collections also account for degradation and include a wide variety of adhesives, results of FTIR collected in reflectance mode are best treated with some caution.

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Birch bark tar was used extensively throughout human history. While later ceramic-based production technologies are known, prehistoric aceramic techniques leave little to no archaeological evidence. Experimental tar production attempts to fill this gap and suggest potential techniques. However, their archaeological relevance is unclear. Through an in-depth biomolecular analysis using Gas Chromatography-Mass Spectrometry, this study attempts to differentiate tars produced using four experimental aceramic techniques: condensation, ash mound, pit roll, and raised structure. In doing so we publish the largest collection of GC-MS results of aceramic birch tars. The results show that pentacyclic triterpenoids, characteristic of birch bark, vary between the production techniques in relation to heating exposure and perhaps the tar collection method. This allows for a tentative identification of tars produced through the condensation and ash mound techniques, which were formed consistently using short periods of heating and collected systematically by scraping. In contrast, tars produced using the pit roll and raised structure techniques do not have consistent molecular signatures. Despite the partial success of Gas Chromatography-Mass Spectrometry, the archaeological relevance is questioned because this technique is only applicable to samples from optimum lipid preservation conditions when a high number of pentacyclic triterpenoids are preserved. Therefore, using Gas Chromatography-Mass Spectrometry to determine the transformation methods of organics, like birch bark, may not be an appropriate standalone technique to fairly discuss the technological capabilities of past populations.

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Osseous barbed and unbarbed points are commonly recovered from the Dutch North Sea and other Mesolithic sites of northern Europe. Interpreted as elements of projectile weaponry, barbed points are considered by archaeologists to be a technological innovation in the hunting equipment of hunter-gatherers. However, debate about their exact use and identification of the targeted prey species is still ongoing. To shed light on the function of these tools, we analysed a sample of 17 artefacts from the Netherlands with a multi-disciplinary approach encompassing morphometric, functional, and chemical analysis. 14C-AMS dating yielded the oldest date for a barbed point from the Dutch coast (⁓13000 cal. BP). The observation of microwear traces preserved on the tools provides solid evidence to interpret the function of barbed and unbarbed points. We show that there were two distinct tool categories. 1) Barbed points hafted with birch tar and animal or vegetal binding were likely projectile tips for terrestrial and aquatic hunting. We provide strong clues to support the link between small barbed points and fishing using wear traces. 2) Points without barbs served as perforators for animal hides. Our results highlight the importance of use-wear and residue analysis to reconstruct prehistoric hunting activities. The functional interpretation of projectile points must also rely on microwear traces and not merely on the association with faunal remains, historical sources, and ethnographic comparisons.@en

The intentional production of birch bark tar by European Neanderthals as early as 190,000 years ago plays an important role in discussions about the technological and behavioural complexity of Pleistocene hominins. However, research is hampered because it is currently unknown how Neanderthals were producing birch tar. There are several different techniques that could have been employed, but these differ in their apparent production complexity, time and resource efficiency. Identifying production processes in the archaeological record is therefore paramount for furthering research on the technical behavioural repertoire. Organic biomarkers, identified with Gas Chromatograph–Mass Spectrometry (GC–MS), have been used to identify possible production processes during the Neolithic. Here we test whether these biomarkers can also distinguish Palaeolithic (aceramic) tar production methods. We produced tar using five different methods and analysed their biomolecular composition with GC–MS. Our results show that the biomarkers used to distinguish Neolithic tar production strategies using ceramic technology cannot be reliably used to identify tar production processes using aceramic Palaeolithic techniques. More experimentation is required to produce a larger reference library of different tars for future comparisons. To achieve this, complete GC–MS datasets must also be made publicly available, as we have done with our data.

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We implement a method from computer sciences to address a challenge in Paleolithic archaeology: how to infer cognition differences from material culture. Archaeological material culture is linked to cognition, and more complex ancient technologies are assumed to have required complex cognition. We present an application of Petri net analysis to compare Neanderthal tar production technologies and tie the results to cognitive requirements. We applied three complexity metrics, each relying on their own unique definitions of complexity, to the modeled production processes. Based on the results, we propose that Neanderthal technical cognition may have been analogous to that of contemporary modern humans. This method also enables us to distinguish the high-order cognitive functions combining traits like planning, inhibitory control, and learning that were likely required by different ancient technological processes. The Petri net approach can contribute to our understanding of technology and cognitive evolution as it can be used on different materials and technologies, across time and species.

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Technological processes, reconstructed from the archaeological record, are used to study the evolution of behaviour and cognition of Neanderthals and early modern humans. In comparisons, technologies that are more complex infer more complex behaviour and cognition. The manufacture of birch bark tar adhesives is regarded as particularly telling and often features in debates about Neanderthal cognition. One method of tar production, the ‘condensation technique’, demonstrates a pathway for Neanderthals to have discovered birch bark tar. However, to improve on the relatively low yield, and to turn tar into a perennial innovation, this method likely needed to be scaled up. Yet, it is currently unknown how scaling Palaeolithic technological processes influences their complexity. We used Petri net models and the Extended Cyclomatic Metric to measure system complexity of birch tar production with a single and three concurrent condensation assemblies. Our results show that changing the number of concurrent tar production assemblies substantially increases the measured complexity. This has potential implications on the behavioural and cognitive capacities required by Neanderthals, such as an increase in cooperation or inhibition control.

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Technologies and their production systems are used by archaeologists and anthropologists to study complexity of socio-technical systems. However, there are several issues that hamper agreement about what constitutes complexity and how we can systematically compare the complexity of production systems. In this work, we propose a novel approach to assess the behavioural and structural complexity of production systems using Petri nets. Petri nets are well-known formal models commonly used in, for example, biological and business process modelling, as well as software engineering. The use of Petri nets overcomes several obstacles of current approaches in archaeology and anthropology, such as the incompatibility of the intrinsic sequential logic of the available methods with inherently non-sequential processes, and the inability to explicitly model activities and resources separately. We test the proposed Petri net modelling approach on two traditional production systems of adhesives made by Ju/’hoan makers from Nyae, Namibia from Ammocharis coranica and Ozoroa schinzii plants. We run simulations in which we assess the complexity of these two adhesive production systems in detail and show how Petri net dynamics reveal the structural and behavioural complexity of different production scenarios. We show that concurrency may be prevalent in the production system of adhesive technologies and discuss how changes in location during the process may serve to control the behavioural complexity of a production system. The approach presented in this paper paves the way for future systematic visualization, analysis, and comparison of ancient production systems, accounting for the inherent complex, concurrent, and action/resource-oriented aspects of such processes.@en

An adhesive is any substance that bonds different materials together. This broad definition includes materials used in everything from hafted stone tools to monumental architecture. In addition, the combination of bonding, plasticity, and insolubility meant that some adhesives were exploited for waterproofing and sealing of materials, as self-adhering inlays and putties, and as paints, varnishes, and inks. Adhesives have a history of at least 200,000 years. Throughout (pre)history and around the world, people used materials, including bitumen/ asphalt, carbohydrate polymers such as starches and gums, natural rubbers, mortars, proteins (from casein, soy, blood, and animal connective tissue), insect and plant resins, and tars made from various barks and woods. Adhesives thus are very diverse and have widely varying properties: they can be tacky, pliable, elastic, brittle, water-resistant, fluid, viscous, clear, dark, and much more. They are a plastic avant la lettre. These properties can and were tweaked by mixing ingredients or by further processing. In the study of archaeological adhesives, their characterization is essential and this is best done with chemical and spectroscopic methods. When larger coherent samples as opposed to single finds are analyzed, adhesive studies can provide data on past technologies, socioeconomic organizations, and environments and raw material availability. Through sourcing and mapping of ingredients and adhesive end products, travel and transfer of materials and knowledge can be illuminated. Additionally, experimental reproductions provide data on technological aspects that otherwise are lost in the archaeological record. An archaeology of adhesives can reveal the transport networks, subsistence, mobility strategies, division of labor, and technological know-how that held societies together.@en

In 2016 raapte amateurarcheologe en -paleontologe Willy van Wingerden uit Honselersdijk op het strand bij Kijkduin een klein stukje vuursteen op met aan één kant een aangehechte zwarte materie. Ze liet de vondst enkele dagen later aan archeoloog Marcel Niekus zien. Die werd direct enthousiast, het zwarte goedje zou wel eens berkenpek kunnen zijn. Daarmee werden in de prehistorie werktuigen vastgezet aan een schacht. Het bleek een topvondst te zijn, vergeleken met de vele ‘gewone’ vuurstenen artefacten die op dit strand werden gevonden. Niemand kon toen nog vermoeden dat deze vondst drie jaar later wetenschappelijk wereldnieuws zou zijn en een nieuw licht zou werpen op het gedrag van de neanderthalers.@en

Adhesive production is one of the earliest forms of transformative technology, predating ceramics and metallurgy by over 150,000 years. The study of the adhesives used by Neandertals and early modern humans currently plays a significant role in debates about human technological and cognitive evolution. Depending on the type of adhesive used, different production sequences were required. These can vary in complexity and would have needed different knowledge, expertise, and resources to manufacture. However, our knowledge of this important technological development is severely hampered by poorly understood taphonomic processes, which affects the preservation and identification of adhesive materials and leads to a research bias. Here we present the results from a 3-year field preservation experiment. Flint flakes hafted and non-hafted with replica adhesives were left to weather naturally on and below the surface at two locations with different soils and climatic conditions. Differential preservation was recorded on a variety of natural adhesives by digitally measuring the surface area of each residue before and after the elapsed time. Residues were further assessed and photographed using metallographic optical microscopy. Results show that certain adhesives preserve to a significantly higher degree than others, while some materials may be more easily overlooked or visually misdiagnosed. We must therefore be aware of both taphonomic and identification biases when discussing ancient adhesive technology. This research provides a first look that will help us understand the disparities between which adhesives were used in the past and what we find in the archaeological record today.

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We report the discovery of a 50,000-y-old birch tar-hafted flint tool found off the present-day coastline of The Netherlands. The production of adhesives and multicomponent tools is considered complex technology and has a prominent place in discussions about the evolution of human behavior. This find provides evidence on the technological capabilities of Neandertals and illuminates the currently debated conditions under which these technologies could be maintained. 14C-accelerator mass spectrometry dating and the geological provenance of the artifact firmly associates it with a host of Middle Paleolithic stone tools and a Neandertal fossil. The find was analyzed using pyrolysis-gas chromatography-mass spectrometry, X-ray micro-computed tomography, and optical light microscopy. The object is a piece of birch tar, encompassing one-third of a flint flake. This find is from northwestern Europe and complements a small set of well-dated and chemically identified adhesives from Middle Paleolithic/Middle Stone Age contexts. Together with data from experiments and other Middle Paleolithic adhesives, it demonstrates that Neandertals mastered complex adhesive production strategies and composite tool use at the northern edge of their range. Thus, a large population size is not a necessary condition for complex behavior and technology. The mitigation of ecological risk, as demonstrated by the challenging conditions during Marine Isotope Stage 4 and 3, provides a better explanation for the transmission and maintenance of technological complexity.@en

Despite a strong increase in the research on hominin percussive tool use, the primary focus in the study of technological behaviour still lies on flaked stone artefacts, especially for the Middle Palaeolithic. This paper aims to contribute to a more thorough understanding of the full spectrum of homi;nin technological behaviour, by presenting a systematic analysis of ground stone tools from the Last Interglacial Middle Palaeolithic site Neumark-Nord 2/2 (NN2/2) (Germany). At NN2/2, coarse gravel- and cobble-sized pieces (n = 351) were sourced from local outcrops of glacial deposits, with a preferential selection for quartzite and sandstone. Low-power use wear analysis and the archaeological context of these finds provide evidence for the possible use of at least 58 pieces for active (hammerstones) and 5 for passive (anvils) percussive tasks, specifically lithic production and potentially bone processing. These grounds stone tools are larger and heavier than the manuports. The hammerstones were preferentially made of quartz and quartzite, while the anvils are mostly of limestone. The limited build-up of use wear on the tools is interpreted as expedient use. The presence of post-depositional surface modifications, their relatively expedient use and their potential application on soft contact materials (e.g. nuts) resulted in a relatively low discernibility of the wear. With expediency being a key factor in Middle Palaeolithic lithic technology, we can expect comparable patterns for other similar-aged ground stone assemblages. Moreover, external factors, like geological context and raw material availability, post-depositional conditions and research focus and intensity, further contribute to the invisibility of such finds in the Middle Palaeolithic record.@en

Adhesives are an important yet often overlooked aspect of human tool use. Previous experiments have shown that compound resin/gum adhesive production by anatomically modern humans was a cognitively demanding task that required advanced use of fire, forward planning, and abstraction among other traits. Yet the oldest known adhesives were produced by Neandertals, not anatomically modern humans. These tar or pitch adhesives are an entirely different material, produced from a distinct, albeit similarly complex process. However, the material properties of these adhesives and the influence of the production process on performance is still unclear. To this end we conducted a series of laboratory based lap shear and impact tests following modern adhesive testing standards and at three different temperatures to measure the strength of pine and birch pitch adhesives. We tested eight different recipes that contain charcoal as an additive (mimicking contamination) or were reduced by boiling for different lengths of time. Lap shear tests were conducted on wood and flint adherends to determine shear strength on different materials, and we conducted high load-rate tests to understand how the same material behaves under impact forces. Our results indicate that both pine and birch pitch adhesives behave similarly at room temperature. Pine pitch is highly sensitive to the addition of charcoal and further heating. Up to a certain extent charcoal additives increases performance, as does extra seething. However, too much charcoal and seething will reduce performance. Similarly, pine pitch is sensitive to ambient temperature changes and it is strongest at 0°C and weakest at 38°C. Adhesive failures occur in a similar manner on flint and wood suggesting the weakest part of a flint-adhesive-wood composite tool may have been the cohesive strength of the adhesive. Finally, pine pitch adhesives may be better suited to resisting high-load rate impacts than shear forces. Our experiments show that pitch production and post-production manipulation are sensitive processes, and to obtain a workable and strong adhesive one requires a deep understanding of the material properties. Our results validate previous archaeological adhesive studies that suggest that the manufacture and use of adhesives was an advanced technological process. @en

We explore if taxonomic analysis of archaeological mollusc assemblages can be used to reconstruct Late Pleistocene (MIS 5–3) coastal environments at Klasies River in South Africa. To obtain a balanced reconstruction, we analyse the large molluscs separately from the so-called incidentals, the small mollusc species. Based on modern mollusc habitat preferences and tolerances we identify four different eco-profiles to help characterise sea surface temperatures and the character of the shore: temperature profile; geographical distribution; substrate; wave interaction. We hypothesise that changes in the Klasies River mollusc community/eco-profiles can be linked to global glacial and interglacial events and we define several testable assumptions. We found that in response to global warming and cooling events, the Klasies River mollusc communities change slightly, yet significantly. Other sources of marine environmental data confirm that average sea surface temperatures gradually decreased, but probably remained within the modern southern east coast range of variation. It appears that coastal sea surface temperatures of the warm Agulhas current were not particularly depressed during the occupation sequence. The character of the coastal topography does change more apparently during the occupation sequence of the sites and with it the mollusc assemblages: from an interglacial rocky shore in the Klasies and two Mossel Bay phases to a more glacial sandy environment during the Howiesons Poort and the MSA III. In conclusion, the temperature tolerance levels of many Klasies River mollusc species are too broad to reflect small changes in sea surface temperatures. However, in conjunction with other eco-profiles and environmental proxies, such as substrate requirements and oxygen isotopes, the temperature approximations are useful, particularly when evaluating large scale sea surface temperature fluctuations. For the characterisation of the shore and substrate we found the eco-profile approach very useful.@en

The production of compound adhesives using disparate ingredients is seen as some of the best evidence of advanced cognition outside of the use of symbolism. Previous field and laboratory testing of adhesives has shown the complexities involved in creating an effective Middle Stone Age glue using Acacia gum. However, it is currently unclear how efficient different adhesive recipes are, how much specific ingredients influence their performance, and how difficult it may have been for those ingredients to be combined to maximum effect. We conducted a series of laboratory-based lap shear and impact tests, following modern adhesion testing standards, to determine the efficacy of compound adhesives, with particular regard to the ingredient ratios. We tested rosin (colophony) and gum adhesives, containing additives of beeswax and ochre in varying ratios. During both lap shear and impact tests compound rosin adhesives performed better than single component rosin adhesives, and pure acacia gum was the strongest. The large difference in performance between each base adhesive and the significant changes in performance that occur due to relatively small changes in ingredient ratios lend further support to the notion that high levels of skill and knowledge were required to consistently produce the most effective adhesives.@en