Huge efforts have been done in the last years on electrochemical and photoelectrochemical reduction of CO ₂ to offer a sustainable route to recycle CO ₂ . A promising route is to electrochemically reduce CO ₂ into CO which, by combination with hydrogen, can be used as a feedstock to different added-value products or fuels. Herein, perpendicular oriented TiO ₂ nanotubes (NTs) on the electrode plate were grown by anodic oxidation of titanium substrate and then decorated by a low loading of silver nanoparticles deposited by sputtering (i.e. Ag/TiO ₂ NTs). Due to their quasi one-dimensional arrangement, TiO ₂ NTs are able to provide higher surface area for Ag adhesion and superior electron transport properties than other Ti substrates (e.g. Ti foil and TiO ₂ nanoparticles), as confirmed by electrochemical (CV, EIS, electrochemical active surface area) and chemical/morphological analysis (FESEM, TEM, EDS). These characteristics together with the role of the TiO ₂ NTs to enhance the stability of CO ₂ ^·- intermediate formed due to titania redox couple (Ti ^IV /Ti ^III ) lead to an improvement of the CO production in the Ag/TiO ₂ NTs electrodes. Particular attention has been devoted to reduce the loading of noble metal in the electrode(14.5 %w/%w) and to increase the catalysts active surface area in order to decrease the required overpotential.

A membrane reactor containing an immobilized heterogeneous catalyst is an alternative for traditional homogeneous-based catalyzed transesterification for biodiesel production. Major problems in homogeneous catalysis are related to catalyst recuperation and soap formation, which can be overcome by using heterogeneous catalysts. Conversion can be increased by a combination of reaction and separation, using membranes with a specific pore size. The aim of this work was to study the performance of different membrane reactors combined with heterogeneous catalysis. The main objectives were: to identify a proper catalyst, to choose the proper immobilization technique, to establish the membrane with the adequate pore size, and to control the reaction and separation process. Amberlyst®15 with acid sites and different types of strontium oxide with basic sites were tested as heterogeneous catalysts. Strontium oxide provided the highest sunflower oil conversion (around 93%) and was easy to immobilize. Two catalytic membrane reactor configurations were investigated, thus confirming the production of several types of methyl esters. The configuration comprising the physical immobilization of the catalyst over the membrane reached a methyl ester yield of > 90 wt%.

Abstract: Mn and Li promoted Rh catalysts supported on SiO₂ with a thin TiO₂ layer were synthesized by stepwise incipient wetness impregnation approach. The thin TiO₂ layer on the surface of SiO₂ was proved to stabilize those small Rh nanoparticles and hinder their agglomeration. The reducibility of Rh on these catalysts depends on Rh particle size as well as the position of manganese oxide, and large Rh nanoparticles with MnO on Rh nanoparticles can be only reduced at an elevated temperature. Catalyst with large Rh particles exhibits a higher CO conversion and higher products selectivity towards long chain hydrocarbons and C2-oxygenates at the expense of decreasing methane formation than a similar catalyst with smaller Rh particles. This was attributed to the synergistic effect of Mn and Li promotion and molar ratio between Rh⁰ and Rh^δ+ sites on the surface of Rh nanoparticles. Moreover, Rh nanoparticles on MnO are proved to be more efficient in promoting hydrogenation of acetaldehyde to ethanol than its counterpart with MnO on Rh nanoparticles. Finally, in order to target high C2-oxygenates selectivity, low reaction temperature together with a low H₂/CO ratio in the feed is recommended. Graphic Abstract: [Figure not available: see fulltext.].

We describe the co-current flow pattern of gas and liquid through micro-fabricated beds of solid and pillars under variable (i) capillary number, (ii) contact angle or wettability and (iii) pillar arrangement, i.e. modifying the distance between pillars or their size and comparing regular with more chaotic systems. Laser-induced fluorescent microscopy and image analysis are used to study the hydrodynamic interactions in terms of dynamics, liquid hold-up, and gas-liquid interfacial area per reactor volume. Those parameters provide insights into the multiphase flow patterns in these systems, how to control them, maximize mass transfer rate and unlock the potential of microreactors to reveal further intrinsic information.

The influence of potassium in Rh on a lanthium promoted zirconia stablised ceria (CZ) catalysts was studied toward NO_xreduction reactivity and selectivity. The results are compared with a Rh/CZ catalyst. The samples were characterised by N₂ adsorption, XRD, SEM, ICP, and H₂-TPR. The study highlighted the importance of stored NO_x regeneration over potassium in determining the overall performance of the Rh/K/CZ catalyst. The NO_x stored over Rh/K/CZ in the previous NO gas stream cannot be regenerated sufficiently during the C₃H₆ gas stream, and stored NO_xgradually decreased from one cycle to the next, resulting in deteriorating performance of Rh/K/CZ. Besides, problem of NO_x slip, the formation of both NH₃ and N₂O (selectivities up to 30% for each side product) were observed by the addition of potassium into the Rh/CZ catalyst system, depending on the reaction conditions applied and the severity of the catalyst deactivation.