The current literature on solid oxide fuel cell and internal combustion engine (SOFC-ICE) integration is focused on the application of advanced combustion technologies operating as bottoming cycles to generate a small load share. This integration approach can pose challenges for ships such as restricted dynamic capabilities and large space and weight requirements. Furthermore, the potential of SOFC-ICE integration for marine power generation has not been explored. Consequently, the current work proposes a novel approach of SOFC-ICE integration for maritime applications, which allows for high-efficiency power generation while the SOFC anode-off gas (AOG) is blended with natural gas (NG) and combusted in a marine spark-ignited (SI) engine for combined power generation. The objective of this paper is to investigate the potential of the proposed SOFC-ICE integration approach with respect to system efficiency, emissions, load sharing, space and weight considerations and load response. In this work, a verified zero-dimensional (0-D) SOFC model, engine experiments and a validated AOG-NG mean value engine model is used. The study found that the SOFC-ICE integration, with a 67–33 power split at 750 kWe power output, yielded the highest efficiency improvement of 8.3% over a conventional marine natural gas engine. Simulation results showed that promising improvements in efficiency of 5.2%, UHC and NOx reductions of about 30% and CO₂ reductions of about 12% can be achieved from a 33–67 SOFC-ICE power split with comparatively much smaller increments in size and weight of 1.7 times. Furthermore, the study concluded that in the proposed SOFC-ICE system for maritime applications, a power split that favours the ICE would significantly improve the dynamic capabilities of the combined system and that the possible sudden and large load changes can be met by the ICE.

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Fundamental studies focusing on the electrode kinetics are essential in understanding the fuel cell operation and optimizing the electrode designs. In this study, we determined the triple-phase boundary (TPB)-based kinetics of hydrogen electrochemical oxidation using nickel patterned electrode experimental data and the Butler-Volmer formalism of the oxidation process. The same kinetics are then incorporated in a cermet electrode electrochemical model to estimate the effective TPB density of the nickel/yittrium-stabilized zirconia cermet anode. The kinetics are found to be of the same order of magnitude as previously determined by the microstructure reconstruction of cermet anode. Simulation results further revealed that the effective TPB density is several orders of magnitude lower than the typically reported physical densities of the cermet anode that possibly suggests that only a minor fraction of the physical TPB is actually required or available to produce the cell current at given cell voltage. The effect of various operating conditions on the anode activation overpotential is also investigated and discussed in this study.

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Carbon deposition is one of the operational problems in hydrocarbon fueled solid oxide fuel cells (SOFCs). Using electrochemical impedance spectroscopy (EIS), experiments are performed to detect carbon formation on button-type cermet Ni-YSZ/YSZ/LSM SOFCs. A mass spectrometer (MS) is used to monitor the outlet gas composition, and the distribution of relaxation times (DRT) is computed to analyse the measured impedance. This work presents preliminary results obtained for H2CH4 mixtures at OCV and 800oC, showing an increase in the mid-frequency range (10-3 and 10-2 s) for methane concentrations exceeding 10 vol%.@en

Solid oxide fuel cells (SOFCs) operate at high temperatures, leading to stringent requirements for the thin ceramic structures in these devices. Heat transfer models aimed to study the temperature distribution within SOFCs are however often simplified by ignoring radiative heat transfer (RHT). A computational model is developed to study the influence of RHT on temperature fields in SOFCs. It is shown that for internal heat transfer in a single channel SOFC, RHT can be safely ignored@en