A next-generation biogeochemical model was developed to explore the impact of the native water source on microbially induced desaturation and precipitation (MIDP) via denitrification. MIDP is a non-disruptive, nature-based ground improvement technique that offers the promise of cost-effective mitigation of earthquake-induced soil liquefaction under and adjacent to existing structures. MIDP leverages native soil bacteria to reduce the potential for liquefaction triggering in the short term through biogenic gas generation (treatment completed within hours to days) and over the longer term through calcium carbonate precipitation (treatment completed in weeks to months). This next-generation biogeochemical model expands earlier modeling to consider multi-phase speciation, bacterial competition, inhibition, and precipitation. The biogeochemical model was used to explore the impact of varying treatment recipes on MIDP products and by-products in a natural seawater environment. The case study presented herein demonstrates the importance of optimizing treatment recipes to minimize unwanted by-products (e.g., H2S production) or incomplete denitrification (e.g., nitrate and nitrite accumulation).@en

The precipitation of calcium carbonate is well studied in many fields of research and industry. Despite the fact that, or perhaps because of the fact that, it is well studied in many fields, different approaches have been used to describe the kinetics of the precipitation process. The aim of this study was to collect and compare the data available in the literature and find a consistent method to describe the kinetics of growth and nucleation of the various polymorphs of calcium carbonate. Inventory of the available data showed that a significant number of the literature sources were incomplete in providing the required information to recalculate the kinetic constants. Using a unified method, we obtained a unique set of parameters to describe the kinetics for growth for calcite, vaterite and amorphous calcium carbonate (ACC) and nucleation for vaterite and ACC. Recalculation of the kinetic constants demonstrated that calcite confirmed there are two growth mechanisms within one polymorph, namely pure spiral growth and spiral growth mixed with surface nucleation. The spiral growth does not show second-order growth, which is typically attributed to it. Re-evaluation of the available nucleation data confirmed the suggested existence of a second pure ACC polymorph with a solubility product between 10−5.87 and 10−5.51 mol2 kgw−2 .@en

We studied the drying behavior of slurries of Markermeer sediments in the Netherlands having different solid compositions. Natural processes such as sand–mud segregation and oxidation of organic matter were mimicked to analyze the effect of changes in sediment composition. Evaporation experiments were performed with soft slurry samples using the Hyprop setup. Soil water retention curves (SWRCs) and hydraulic conductivity curves (HCCs) were determined as a function of the water ratio (WR, defined as volume of water/volume of solids). The sediment remained close to saturation until the end of the experiments. The Atterberg limits reduced significantly after sediment treatment involving drying at 50 °C, rewetting, and chemical oxidation. Furthermore, the oxidized sediment lost capacity to retain water. The SWRCs of sandy and oxidized clays were steeper, and fine-textured sediments showed large water ratios. At low matric suctions, the water retention capacity of the upper sediment samples containing more labile organic matter was larger than that of the sediment underneath. Clear correlations were found between van Genuchten parameters and the degree of degradation of the organic matter. The hydraulic conductivity of fine-textured samples with less labile organics was larger. The results give insight into the drying behavior of Markermeer sediment, currently used to build wetlands.

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The characteristics of clayey suspensions, majorly composed of quartz microparticles, in the presence of anionic and cationic polyelectrolytes were investigated using different techniques. A wide range of clay concentrations was used, i.e., from 0.07 to 1000 g/L for different experimental techniques, based on the fact that the clay concentration possible to analyze with selected experimental methods was significantly different. The optimum flocculant to clay ratio was defined as the ratio that gives the fastest initial floc growth by static light scattering or fastest initial settling velocity by settling column experiments. In case of anionic polyelectrolyte, it was observed that the optimum flocculant dose depends on the amount of cations present in the system. For suspensions made with demi-water, a lower optimum flocculant dose (<1 mg/g) than for suspensions prepared in tap water (2.28 mg/g) was observed. At these lower salinities, the supernatant remained turbid in all the experiments and was, therefore, not a good measure for optimal anionic based flocculation. The equilibrium floc size at a given shear rate was found to be independent on the shear history of the floc and only dependent on the current applied shear. This was confirmed by both light scattering and rheological analysis. In case of cationic polyelectrolyte, the optimum flocculant ratio (5–6 mg/g) corresponded to the ratio that gives the lowest electrophoretic mobility for each clay concentration and to the ratio that gives the fastest settling velocity for the highest clay concentrations (12–15 g/L), where static light scattering measurements were not possible. All investigation techniques, therefore, proved to be good indicators for predicting the optimum flocculant to clay ratio. For the lowest concentrations (1.75–8.7 g/L) studied by settling column measurements, the optimum flocculant ratio was observed to increase with decreasing clay concentration, for fixed mixing conditions. The optimum flocculant to clay ratio was not always corresponding to the clearest supernatant and the size of flocs at optimum dosage was dependent on the mixing efficiency. The equilibrium floc size at a given shear rate was found to be dependent on the shear history of the floc and the current applied shear. This was confirmed by both light scattering and rheological analysis.

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Many low-lying peatlands in delta areas undergo significant subsidence due to drainage for agricultural purposes. Subsidence may be attributed to shrinkage, consolidation or oxidation. At the same time the canals and ditches are regularly dredged to maintain water quality and drainage capacity. Often these dredged sediments are placed on land, which may help to slow down subsidence. In this study subsidence of organic sediments was monitored for a period of three years. The sediments were dredged from lakes and canals in the peatlands of Wormer- en Jisperveld, in the Netherlands and placed in an on-land constructed depot. Samples were collected at regular time intervals to measure water content and organic content. Additionally, laboratory tests were performed to characterize the organic sediments and determine the compression, consolidation, shrinkage and water retention characteristics under various oxidizing conditions. The laboratory tests showed that oxidation can significantly affect the compression, consolidation, water retention and shrinkage characteristics of organic soils. However, monitoring results in the field showed that the major part of the subsidence, which occurred within the three years of this study, could be attributed to shrinkage of the dredged sediments and the remainder to consolidation of the underlying peat layers, while the organic matter content did not change significantly.

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Microbially induced carbonate precipitation (MICP) through denitrification can potentially be applied as a bio-based ground improvement technique. Two strategies involving multiple batch treatments in a modified triaxial test setup were used to study the process efficiency. Both strategies aim to achieve 1 weight percentage (% by weight) of precipitated calcium carbonate (CaCO₃) and differ in number of flushes, hydraulic residence time, and substrate concentrations. In the experiment with few flushes and high substrate concentrations the microbial process was inhibited, only 0.28% by weight CaCO₃ was measured in the sand after 5 weeks of treatment. The regime with many flushes and low substrate concentrations stimulated microbial growth resulting in 0.65% by weight CaCO₃ within the same time period. Biomass growth and nitrogen gas production were stable throughout the experiment at low concentration, reducing the hydraulic conductivity of the sand, which eventually led to clogging. Precipitation rates up to 0.26% by weight/day CaCO₃ were observed. Applying a suitable substrate regime and residence time is important to limit inhibition and maintain the cell activity, allow for an efficient conversion, and generate a good precipitation rate.

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Land subsidence in low-lying peatlands can be caused by shrinkage and organic matter oxidation. When these areas have networks of ditches and canals for drainage purposes, the sediments that accumulate in the waterways can be used to reverse the process of land subsidence. The objective of this study is to understand how dredged sediments can be used to reverse the process of land subsidence by analysing the contribution of shrinkage and organic matter mineralization to the subsidence observed in an upland deposit. A deposit of dredged sediments in the Wormer- en Jisperveld—North Holland, the Netherlands—was characterized during 17 months in terms of subsidence of the sediments, subsidence of the soil underlying the deposit, geotechnical water content, organic matter content, type of organic matter and nutrients. The deposit was filled to a height of 195 cm, and after 17 months, the subsidence of the sediments was 88 cm. In addition, a subsidence of 19.5 cm of the underlying soil was observed. Subsidence could be attributed to shrinkage since no significant changes in the organic matter content and total organic carbon were observed. The type of organic matter changed in the direction of humification until winter 2014, stabilized from winter 2014 to spring 2015 and changed in the direction of mineralization after the spring of 2015. Subsidence of dredged sediments in upland deposits is caused by shrinkage during the first 17 months. The solution of spreading thinner layers of sediments over the land to decrease the subsidence rates should be explored since the pressure of the deposit on the underlying soil caused an extra subsidence of 19.5 cm.

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Desaturation by biogenic gas formation can significantly affect the hydro-mechanical behaviour of soil. The high compressibility of the gas dampens pore pressure build up during both monotonic and cyclic undrained loading. Stimulating biogenic gas production therefore has potential as a ground improvement method to mitigate the risk of both static liquefaction and earthquake induced liquefaction. However, gas generated below the ground water table at shallow depth may also constitute a hazard for offshore foundations and terrestrial deposits, as a sudden release of trapped gas may cause instability. In order to evaluate the potential use of biogenic gas for geotechnical applications it is essential to be able to predict gas production and assess its effect on the hydro-mechanical behaviour of a soil. A basic theoretical framework to estimate the volume of gas produced by a biogenic process and the related degree of saturation, experimental results on the rate of gas generation, and its impact on soil behavior are presented herein.

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Cracks in drying soils have detrimental effects on the integrity of geotechnical structures. The evaporation rate is recognized to play an important role in fracture generation, having a direct impact on the amount of cracks produced. This investigation examined the drying behaviour of a clay with different initial water contents and under different evaporative conditions. Small-scale evaporation experiments were carried out using a river clay and commercially available suction-measuring equipment. The results showed that the initial conditions have great influence on the drying performance of a soil, which can be partly attributed to the influence of the surface texture and the pore structure. It was observed that under certain circumstances, the evaporation of a soil surface can be higher than that of open water. The different evaporation rates had a marked effect on the water distributions with depth within the soil. The evaporation rate also produced a dynamic response of the soil-water retention curve.

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Tensile strength is one of the main variables involved in the formation of desiccation fractures in clay. It is known that the drying rate affects the final amount of cracks in a soil, which points out to the potential influence of rate effects in soil cracking. The effects might be related to variations in the tensile strength affected by different shrinkage rates. A limited amount of investigations have looked at the impact of strain rate on the tensile strength of soil. This study examines the combined effects of pull rates and high water contents on the tensile strength of a clay. Particle Image Velocimetry analysis was also carried out on pictures taken during the tests to examine the strains generated. It was found that the effect of pull rate on the tensile strength of the clay was negligible compared to the effect of the water content. Pull rate did affect the stiffness response of the soil. The findings revealed that the influence of the evaporation rate on soil fracturing might be related more to the rate dependency of the stiffness rather than to significant changes in tensile strength.

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We all know the Dutch story of the 'never-ending spiral' of land subsidence caused by drainage and oxidation of peat. But how does it really work and what can be expected for the future? Anne-Catherine Dieudonné explains the fundamentals and addresses the current frontiers of research. Is there indeed no end to subsiding peatlands?@en

Waterways and lakes in low-lying delta areas require regular dredging for maintenance. Often these sediments are placed on land, where they are allowed to ripen through a combination of drainage, consolidation and evaporation. When cracks develop during desiccation, the physical response of the soil is affected by changes in the overall strength, stiffness and permeability of the material. To better identify how cracks form and propagate, a series of tests was carried out in a controlled laboratory environment on samples of drying clay slurries under different initial and boundary conditions. The outcomes of this study indicate that the results from laboratory small scale models must be carefully analyzed, as they depend on the area and the thickness of the sample. However, common features from the different tests can be identified, which are mostly related to the intrinsic behavior of the material. For instance, the water content at which cracks initiate depends mostly on the drying rate and not only on the initial water content. Typically for the clayey soil investigated, the cracking water content is well above the shrinkage limit and in some instances even above the liquid limit. Cracks can form anywhere a defect is encountered, but it was observed that they propagate in horizontal directions below the soil surface. On the soil surface they tend to intersect with each other perpendicularly, suggesting that they are dominated by a tensile stress regime. Shear stresses also influence the response, but mainly near the boundaries of the samples, due to the interface friction.

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Starch is a natural polymer which is commonly used as a cooking ingredient. The renewability and bio-degradability of starch has made it an interesting material for industrial applications, such as production of bioplastic. This paper introduces the application of corn starch in the production of a novel construction material, named CoRncrete. CoRncrete is formed by mixing corn starch with sand and water. The mixture appears to be self-compacting when wet. The mixture is poured in a mould and then heated in a microwave or an oven. This heating causes a gelatinisation process which results in a hardened material having compressive strength up to 26 MPa. The factors affecting the strength of hardened CoRncrete such as water content, sand aggregate size and heating procedure have been studied. The degradation and sustainability aspects of CoRncrete are elucidated and limitations in the potential application of this material are discussed.

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Purpose: In delta areas, dense networks of canals have been developed through time and have to be periodically dredged. Lowering the groundwater level in delta areas deepens the aerobic zone, leading to the oxidation of organic matter and possibly to land subsidence. The use of the dredged sediments on land can be a solution to mitigate land subsidence in delta areas. Materials and methods: Five types of dredged sediments with different organic matter content and particle size distribution were dewatered for 7 days and then submitted to biochemical ripening during 141 days on a laboratorial scale with constant temperature and relative humidity. The functional properties analysed were the type and content of organic matter, pH, total C, N, P and S, dry bulk density, water retention capacity, aggregate stability and load-bearing capacity. Results and discussion: After biochemical ripening, there was no significant loss in the mass of organic matter but there was an increase in the fraction of stable organic compounds, observed by an increase in oxygen-bearing compounds and a decrease in hydrocarbons during biochemical ripening. The pH was not affected by biochemical ripening, and the total C, N, P and S concentrations are high and therefore the dredged sediments can improve the quality of the land. Most volume lost during dewatering and biochemical ripening can be attributed to the loss of water. The water retention capacity of the dredged sediments changed with biochemical ripening. The soils formed from biochemical ripening have very stable aggregates, and its load-bearing capacity is enough to sustain cattle and tractors. Conclusions: Most volume lost during dewatering and biochemical ripening can be attributed to the loss of water and not organic matter. Therefore, the studied dredged sediments have potential to mitigate land subsidence in delta areas when spread on land.

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Sediment is becoming scarce. Therefore, soft sediments are progressively being used for nature building. The MarkerWadden is an example of an ongoing Building with Nature (BwN) project which aims to improve the ecology of Lake Markermeer (The Netherlands) by creating a wetland with the cohesive sediments from the bed of the lake. It represents one of the first projects using fresh unconsolidated mud as a filling material. However, building with these fine sediments represents a great challenge, because of their complex properties.@en

Given the increasing scarcity of resources, a transition from the traditional linear “make-take-waste” production scenario to a circular model is essential to be able to meet the needs of future generations. In the circular economy concept1 products are designed in such a way that their components fit as nutrients in either the biological cycle – biodegradable after use, recycled, and regrown by nature itself – or the technical cycle of industrial non-renewable materials whose finite stocks need to be secured by high-level recycling.@en

Desiccation cracks are usually thought to start from the surface of an evaporating soil layer, and the available simplified models for crack initiation and propagation are based on this hypothesis. On the contrary, experimental results on a Dutch river clay showed that cracks in an evaporating soil layer may start and propagate below the surface, confirming earlier findings by other researchers. A simple one-dimensional model was set up to analyse the consequences of different hypotheses about the material behaviour on the crack onset in a homogenous soil layer undergoing surface drying. The results of the model show that dependence of the material behaviour on the rate of water content change is a necessary requirement for cracks to initiate below the surface. The conclusion suggests that, to properly understand cracking in an evaporating soil layer, an intrinsic time scale for the mechanical response must be accounted for, among all the other factors which were previously highlighted by other researchers. The key factor to predict crack onset below the surface is the dependence of the drying branch of the water retention curve of the compressible soil on the rate of drying, which would be justified by a rate dependent fabric evolution.@en

The process of microbially induced carbonate precipitation (MICP) by denitrification was investigated in relation to its potential use as a ground improvement method. Liquid batch experiments indicated that the substrate solution had an optimum carbon–nitrogen ratio of 1·6 and confirmed that combining nitrate reduction and calcium carbonate precipitation leads to an efficient conversion, at which the pH is buffered slightly below 7 and the accumulation of toxic intermediate nitrogen compounds is limited. Sand column experiments confirmed that the volume and distribution of the gas phase strongly depend on the stress conditions. The produced gas volume is inversely related to the pore pressure and can be predicted based on a mass balance analysis, assuming conservation of mass and using theoretical laws of physics. At low pore pressure, the gas formed and accumulated at the top of the column, whereas calcium carbonate precipitation occurred mostly at the bottom near the substrate inlet; an excess amount of gas was produced, which vented from the sand columns and induced cracks in the sand at low confining pressures, which negatively affected the sand-stabilising effect of the calcium carbonate minerals. @en

Microbially induced precipitation is a multi disciplinary field combining biology, chemistry and geotechnology. An example of such a process is biogrout, where high concentrations of calcium ions together with biological carbonate production is used to precipitate calcium carbonate in soils. To be able to describe the precipitation rate, the chemical saturation, which is needed for the driving force of precipitation, must be calculated properly. A small deviation in the saturation can lead to large deviations n crystal growth and nucleation rates Calculating the saturation in a carbonate system requires ion speciation and activity corrections to be taken into account. There are many activity correction methods available, most of which are only valid up to a moderate ionic strength of the solution ( < 0.1 mol kg^-1) Some of these methods are also developed for equimolar electrolytes. This is in contrast with the biogrout process which involves solutions with high ionic strengths and calcium and carbonate concentrations which are initially strongly non-equimolar Additionally, the calculation of saturation can be simplified by ignoring several ion complexes and water self-ionization. However, simplifications must be made with care as the speciation is strongly non linear. This means that any simplification may have a significant impact on the saturation This research aimed to compare several softwares using different activity correction methods, e.g PhreeqC, as well as a full speciation scheme coupled with an activity correction method suitable for solutions with a high ionic strength Their performance for solutions with ionic strength and non-equimolar concentrations are tested Additionally, this research aims to provide a speciation scheme for such solutions that is simplified as much as possible without significant accuracy loss for the chemical saturation@en