Carbon dioxide capture and storage in subsurface geological formations is a potential solution to limit anthropogenic CO₂ emissions and combat global warming. Depleted gas fields offer significant CO₂ storage volumes; however, injection of CO₂ into these reservoirs poses some potential challenges for the injectivity, containment and well/facility integrity due to low temperatures caused by isenthalpic expansion of CO₂. A key injectivity risk is due to possible formation of hydrates at the low expected temperatures. This study aims to address main causes of CO₂ hydrate formation and its impact on permeability of porous media. This review highlights the current state of knowledge in the literature while emphasizing the need to bridge existing gaps in derisking CO₂ injection into (depleted) low-pressure gas reservoirs. In summary, according to the existing literature, the potential for hydrate formation is assessed to be credible. Current industry solutions exist to manage this risk; however, they are costly and energy intensive. Future research will be needed to provide capabilities to manage this risk more efficiently.

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With the intensification of global climate change and the growing demand for the Sustainable Development Goals (SDGs), dual-carbon policies are on the rise globally, bringing new challenges and opportunities to the energy industry. Focusing on the photovoltaic (PV) industry, this study carries out a carbon footprint analysis in the context of dual-carbon to gain a comprehensive understanding of the current status of PV modules in terms of carbon emissions and emission reduction measures. This paper firstly summarizes the development of the PV industry, and deeply analyzes the relevant theories and methods of carbon footprint assessment and accounting system. Then, it systematically evaluates the carbon emissions of crystalline silicon PV modules throughout their life cycle, and based on this, it puts forward suggestions on strategies to reduce the carbon footprint. Finally, the opportunities and challenges that the PV industry may encounter in the process of moving towards a low-carbon future are discussed to provide a reference for decision-making and practice in this field.@en

CO2 storage in deep saline aquifers is an effective strategy for reducing greenhouse gas emission. However, salt precipitation triggered by evaporation of water into injected dry CO2 causes injectivity reduction. Predicting the distribution of precipitated salts and their impact on near-well permeability remains challenging. Therefore, a detailed investigation of the interactions between salt precipitation and porous domain is essential for of revealing the mechanisms of pore blockage due to salt crystallization. Through series of microfluidic experiments, direct observations, coupled with detailed imaging processing, form the basis for explaining these phenomena and provide a relationship between water and salt saturations, highlighting the critical roles played by local capillary-driven flow and water film along grains in influencing water relocation. The results reveal two distinct types of salt crystallization: occurring inside the brine with smooth edges and at the CO2-brine interface with rough edges. Furthermore, the impact of local heterogeneity and surface wettability on salt precipitation patterns is discussed. The transition region between the porous domains and inlet/outlet channels exhibits brine backflow and a larger amount of salt accumulation. This paper presents a comprehensive analysis of the dynamic process of salt dry-out occurring during CO2 injection at the pore scale.@en

Low salinity water flooding is a common technique for enhancing oil recovery; however, the mechanism behind the low-salinity effect, positive or negative, is still not fully understood. In the proposed mechanisms, osmosis and emulsification are considered as two potential reasons for explaining the oil remobilization, but the specific contributions on the remobilization are not well studied at pore-scale. In this article, we performed a series of microfluidic experiments to investigate the movement of constrained oil between invading low-salinity brine and residual high-salinity brine. We find that various salinity contrasts over oil films cause different water fluxes through the oil and swelling areas of the trapped brine, resulting in the relocation of oil phases within the pore spaces. A higher salinity contrast (1.7-170 g/L salt concentrations) provides a faster water penetration in oil phases. In the presence of an oil-soluble surfactant, spontaneous emulsification occurs at the interface of low-salinity brine/oil, which enhances almost 100 times the water flux in two oil phases (n-heptane and n-dodecane). We directly observe pore-scale spontaneous emulsification at the low-salinity brine/oil interface but not at the high-salinity brine/oil interface. Furthermore, two scenarios for explaining water transport through the oil phase are proposed: water diffusion due to chemical potential gradient and water transport via reverse micelle or microemulsions movement.

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Understanding the kinetics of CO2 hydrate formation and the resulting saturation of the hydrate in porous rocks is crucial for processes such as the storage of CO2 in underground formations. Nevertheless, to date, there is no established procedure that utilizes a medical CT scanner for quantifying gas hydrate saturation in core samples during the growth stage. This study proposes a methodology for estimating hydrate saturation using a medical CT scanner during the injection of CO2 into porous media. This method uses the mean area obtained from the image analysis to calculate the dynamic profile of water and the CO2 hydrate along the length of the sandstone core. To demonstrate the technique, core flooding experiments were conducted to form gas hydrates in semibrine-saturated sandstone cores.@en