A phenomenon that compromises the health of city inhabitants is the urban heat island (UHI) effect. This effect is mainly driven by thermal radiation and designates the typically higher air temperature in cities compared to the surrounding rural areas. Over 55% of the world’s population lives in cities, and with this percentage set to rise to more than 65% by 2050, it is vital to model the urban climate to be able to mitigate the UHI-effect. In this study, the surface energy balance (SEB) is modeled in urban environments using a one-way coupled RANS 𝑘 − 𝜖 approach in order to gain fundamental insights into the influence of thermal radiation on the UHI-effect. The SEB model is built mechanism-by-mechanism, adding in different physical mechanisms one at a time and validating the model at each step with literature- or theoretical values. The SEB model showed a good agreement with experimentally found values for the effect of surface irregularity of an urban structure on the absorption and reflection of incident solar radiation. A good agreement was also found with theoretical values for the longwave radiation and conductive heat flux part of the SEB model. Subsequently, a study was done on a 2D street canyon to compare the model with literature results. This study showed a good agreement for the radiative fluxes, but a lesser agreement for the conductive- and sensible heat fluxes. A more complex scenario of an intersection between buildings was studied. It was shown that the longwave trapping effect is highly correlated with building height. Finally, the effect of wall heating on flow characteristics in a 2D street canyon was examined. For homogeneously heated walls, the SEB model showed a relatively good agreement with literature results. A study was also done with non-homogeneously heated walls. This study showed less realistic results and should be further investigated in further research.