The surface of supported heterogeneous catalysts often contains adsorbed water and hydroxyl groups even when water is not directly added to the reaction stream. Nonetheless, the reactivity of adsorbed water and hydroxyl groups is rarely considered. We demonstrate that water and hydroxyl groups can not only directly participate in the catalytic oxidation processes but are also able to generate and stabilize the catalytically active metal-oxide interface. We show that the reduction of Pt-Fe-supported catalysts with hydrogen in the presence of adsorbed water or steam allows for achieving one of the highest preferential carbon monoxide oxidation activities at ambient temperature. These conditions create active iron-associated hydroxyl groups next to platinum nanoparticles with enhanced reactivity towards carbon monoxide oxidation. Density functional theory calculations suggest that hydroxylation of oxidic iron species stabilizes the FeO_x(OH)_y/Pt interface, via strong metal-support interaction, which is confirmed by chemisorption measurements. Kinetic experiments, including those with ¹⁸O-labeled water, in combination with operando infrared spectroscopy, show that water and hydroxyl groups directly participate in preferential carbon monoxide oxidation. A quantitative correlation between the catalytic activity of Pt-FeO_x(OH)_y/γ-Al₂O₃ catalysts and the Fe²⁺ concentration, obtained using operando X-ray absorption spectroscopy, shows that the number of active Fe²⁺ sites and the carbon monoxide oxidation rate per active site can be significantly increased by water-assisted pretreatment with hydrogen. This work provides a new example of positive role of strong metal-support interaction for the design of more active catalysts.

The performance of functional materials is either driven or limited by nanoscopic heterogeneities distributed throughout the material’s volume. To better our understanding of these materials, we need characterization tools that allow us to determine the nature and distribution of these heterogeneities in their native geometry in 3D. Here, we introduce a method based on x-ray near-edge spectroscopy, ptychographic x-ray computed nanotomography, and sparsity techniques. The method allows the acquisition of quantitative multimodal tomograms of representative sample volumes at sub–30 nm half-period spatial resolution within practical acquisition times, which enables local structure refinements in complex geometries. To demonstrate the method’s capabilities, we investigated the transformation of vanadium phosphorus oxide catalysts with industrial use. We observe changes from the micrometer to the atomic level and the formation of a location-specific defect so far only theorized. These results led to a reevaluation of these catalysts used in the production of plastics.

Catalytic systems based on supported noble metals are extensively studied because of their widespread application. Discussions remain about the nature of the active species, whether they are atomically dispersed or nanoparticles, and their reactivity. In this work, combining in situ/operando spectroscopy with theoretical modeling, we propose a phase diagram of atomically dispersed platinum on ceria, demonstrating that it reversibly changes from PtIVO2 to PtIIO as a function of temperature and oxygen partial pressure. The phase diagram helps identify the stability domain of each species, while spectroscopies provide a quantitative evaluation depending on the reaction conditions. Finally, our results show that high-temperature activation in the presence of steam of supported atomically dispersed platinum enhances the activity toward low-temperature carbon monoxide oxidation because it promotes aggregation into nanoparticles. This work highlights the structure-activity relationship in supported metal catalysts and proposes a suitable approach to determine the amount of each species before the investigation of the reaction mechanism.

In spite of numerous works in the field of chemical valorization of carbon dioxide into methanol, the nature of high activity of Cu/ZnO catalysts, including the reaction mechanism and the structure of the catalyst active site, remains the subject of intensive debate. By using high-pressure operando techniques: steady-state isotope transient kinetic analysis coupled with infrared spectroscopy, together with time-resolved X-ray absorption spectroscopy and X-ray powder diffraction, and supported by electron microscopy and theoretical modeling, we present direct evidence that zinc formate is the principal observable reactive intermediate, which in the presence of hydrogen converts into methanol. Our results indicate that the copper–zinc alloy undergoes oxidation under reaction conditions into zinc formate, zinc oxide and metallic copper. The intimate contact between zinc and copper phases facilitates zinc formate formation and its hydrogenation by hydrogen to methanol.