NASA’s ACS3 mission will be the first Earth-bound solar-sail mission to fly so-called calibration steering laws. These steering laws are designed to expose the sailcraft to a variety of dynamical conditions to isolate the effects of different parameters on the dynamics, thereby facilitating the estimation of these parameters. This paper presents the set of candidate calibration steering laws of ACS3, highlighting their operational challenges and impact on the estimation of the sail’s reflectivity and specularity. The results show that, for a conservative GPS position accuracy of 10 m, accurate estimation of the reflectivity and specularity with uncertainties in the order of 10−4 − 10−3 can be achieved by flying any of the proposed calibration laws. However, ACS3’s calibration steering laws were also found to introduce operational challenges that may hinder their implementation for extended periods of time. In particular, the decreased power generation capability of solar arrays was found to be the most severe operational challenge for two out of the five ACS3’s calibration laws analysed. @en