The continued reliance on fossil fuels to satisfy the world energy demand is leading to climate change, accelerating the melting of polar ice shelf, and is dealing irreversible damage to the flora and fauna of earth, to name few of the adverse effects from fossil fuel utilisation. In addition to not being renewable, fossil-fuel resources are also limited. Therefore these resources cannot meet the energy demand at some point in future. The most plausible way is to utilise renewable sources of energy to meet the increasing demand of energy. The Sun, our closest star is the answer to this demand. Utilising the abundant solar radiation arriving at earth to generate electricity is a great way. A photovoltaic (PV) solar cell can achieve this by converting the incident sunlight directly to electricity..... @en

Passivated contact based on a thin interfacial oxide and a highly doped polysilicon layer has emerged as the next evolutionary step to increase the efficiencies of industrial silicon solar cells. To take maximum advantage from this layer stack, it is vital to limit the losses at the metal polysilicon interface, which can be quantified as metal polysilicon recombination current density (J _0met) and contact resistivity. In cell concepts, wherein a large variety of silicon substrate surface finish can be obtained, it is essential to know how the surface finish affects the J _0met and contact resistivity. Herein, commercially available fire through silver paste and the metal-polysilicon recombination current densities and contact resistivity are used for three different silicon substrate surface finishes, namely: planar or saw damage etched (SDE), chemically polished in acidic solution and alkaline pyramidal textured. Contact resistivity values below 3 mΩ cm² with J _0met in order of the recombination current density of the doped region (J _0pass) are obtained for samples with planar surface for both 150 and 200 nm n⁺ polysilicon layer thicknesses. The results presented in this work show that the samples with flat substrate morphology outperform the samples with textured surfaces.

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In this article, we investigate the passivation quality and electrical contact properties for samples with a 150 nm thick n+ polysilicon layer in comparison to samples with a phosphorus diffused layer. High level of passivation is achieved for the samples with n+ polysilicon layer and an interfacial oxide underneath it. The contact properties with screen-printed fire-through silver paste are excellent (no additional recombination from metallization and specific contact resistivity (ρc) ≤ 2 mΩ·cm2) for the samples with the polysilicon layers. Fast-firing peak temperature was varied during the contact formation process; this was done to see the trend in the contact properties with the change in the thermal budget. The differences in the J0met and ρc for the two different kinds of samples are explained with the help of high-resolution scanning electron microscope imaging. Finally, we prepare M2-sized n-passivated emitter rear totally (PERT) diffused solar cells with a 150 nm thick n+ polysilicon based passivated rear contact. The best cell achieved an efficiency of 21.64%, with a Voc of 686 mV and fill factor of 80.2%.

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We have metallised n+ polysilicon passivated layer structures deposited by Low Pressure Chemical Vapor Deposition (LPCVD) with silver pastes. We analysed recombination at the metal contacts by photoluminescence imaging of metallised lifetime samples and found for the best paste, metal semiconductor recombination current density values (J0met) below 70 fA/cm², with contact resistivity below 2 mΩcm². To our knowledge, these are among the lowest values reported so far for full size M2 wafers with 150 nm thin polysilicon layer and wet chemical thin oxide. We also studied the effect of the peak firing temperature on the J0met and contact resistivity in this work. Further, we performed Scanning Electron Microscopy to further understand the silver polysilicon interface.

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This work investigates how the thickness of the polysilicon layer and temperatures during contact sintering influence the properties of SiO_x/polysilicon passivated contacts. The n⁺ polysilicon layers deposited by low-pressure chemical vapor deposition (LPCVD) on top of a thin wet chemically grown interface oxide layer providing chemical and field-effect passivation on n-type monocrystalline silicon wafers are investigated. Three different polysilicon layer thicknesses of 50, 100, and 150 nm are considered in this work. A high level of passivation with implied V_oc values above 735 mV and J₀₁ below 5 fA cm⁻² is obtained for symmetric lifetime test samples. These samples are used to investigate the interaction of the silver paste with the polysilicon layer at different fast firing peak temperatures. Reduction in polysilicon layer thickness leads to an increase in contact resistivity as well as in J_0met. Excellent J_0met values of the order of J₀₁ with contact resistivity values below 2 mΩ cm² are obtained for samples with polysilicon layers of 100 and 150 nm thickness.

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We have printed firing through silver paste on n+ polysilicon passivated layer structures deposited by Low Pressure Chemical Vapor Deposition (LPCVD). We analysed recombination at the metal contacts by photoluminescence imaging of metallised lifetime samples and found for the best paste, metal semiconductor recombination current density values (J0met) below 100 fA/cm². To our knowledge, these are among the lowest values reported so far for full size M2 wafers with 150 nm thin polysilicon layer. On samples metallised with standard commercial pastes for diffused emitters, we observed higher J0met values, while contact resistivity was acceptable for all samples. We also studied the effect of the peak firing temperature on the J0met and contact resistivity in this work. Further, we compared the impact of deep and shallow doping profiles on the passivation and the J0met values.

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