Developing high-performance carbonaceous anode materials for sodium-ion batteries (SIBs) is still a grand quest for a more sustainable future of energy storage. Introducing sulfur within a carbon framework is one of the most promising attempts toward the development of highly efficient anode materials. Herein, a microporous sulfur-rich carbon anode obtained from a liquid sulfur-containing oligomer is introduced. The sodium storage mechanism shifts from surface-controlled to diffusion-controlled at higher synthesis temperatures. The different storage mechanisms and electrode performances are found to be independent of the bare electrode material's interplanar spacing. Therefore, these differences are attributed to an increased microporosity and a thiophene-rich chemical environment. The combination of these properties enables extending the plateau region to higher potential and achieving reversible overpotential sodium storage. Moreover, in-operando small-angle X-ray scattering (SAXS) reveals reversible electron density variations within the pore structure, in good agreement with the pore-filling sodium storage mechanism occurring in hard carbons (HCs). Eventually, the depicted framework will enable the design of high-performance anode materials for sodium-ion batteries with competitive energy density.

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Geothermal is an important renewable energy source, but the high cost of drilling limits its popularization. The oilfield area is rich in geothermal resources and has a large number of high-temperature abandoned wells. It is an economic and effective method to transform the abandoned wells into geothermal wells. At present, the heat extraction research of abandoned wells mostly focuses on single-well closed systems, while the most common in oilfields is the well patterns open system, which involves the flow and heat extraction of oil-water multiphase. More, the main utilization mode of oilfield geothermal is heating, which is an intermittent operation, and the existence of the heat recovery period makes the solution process more complicated compared to continuous production. Therefore, the numerical simulation of oil-water two-phase and the scheme optimization under intermittent operation are the key problems in the current oilfields geothermal research, that is, it should be made clear what the effects of operation parameters are and how to get the optimization design for the intermittent mining of heat-oil cogeneration from abandoned wells. For this reason, the oil-water two-phase heat-flow coupling model and economic evaluation model are established. Then, database is established through parameter sensitivity analysis, and multi-objective optimization research is carried out on the lifetime and economic benefits using Non Sorting Genetic Algorithm II (NSGA-II). The results show that economic benefit and end-point temperature of the optimized scheme are enhanced by 6.75 million US dollars and 7.10 K after 15-year production, respectively. The heat-oil cogeneration performance is superior, so the influence of oil phase cannot be ignored in the heating process of the well patterns system for oilfield geothermal production.

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The efficient development of hydrothermal resource is an important focus in the global geothermal industry. A novel hydrothermal open-loop geothermal system in a multi-lateral horizontal well is presented to achieve the simultaneous exploitation of multi-layer reservoirs and accelerate the large-scale development of the hydrothermal resource. To investigate the detailed performance of the novel geothermal system, a novel 3D fluid flow and heat transfer numerical model is established based on the local thermal non-equilibrium and dual porosity theories. The flow and temperature fields are analyzed, while the pressure and temperature interferences between the lateral wellbores of the multi-lateral horizontal well system are comprehensively investigated. The influences of the injection flow rate, lateral-wellbore number, spacing between the injection segment and the main wellbore, fracture aperture on the heat extraction are studied. Furthermore, the thermal characteristics of the novel geothermal system and traditional doublet well system are compared for the first time. The investigation indicates that the flow impedance of the novel geothermal system can decrease by 75.38%, and its energy efficiency reaches 8 times that of the doublet well system. The findings can provide a key reference for scientific research and application of the novel and traditional geothermal systems.

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As a kind of clean renewable energy, the production and utilization of geothermal resources can make a great contribution to optimizing the energy structure and energy conservation and emission reduction. The circulating heat extraction process of working fluid will disturb the equilibrium state of physical and chemical fields inside the reservoir, and involve the mutual coupling of heat transfer, flow, stress, and chemical reaction. Revealing the coupling mechanism of flow and heat transfer inside the reservoir during geothermal exploitation can provide important theoretical support for the efficient exploitation of geothermal resources. This paper reviews the research advances of the multi-field coupling model in the reservoir during geothermal production over the past 40 years. The thrust of this paper is on objective analysis and evaluation of the importance of each coupling process and its influence on reservoir heat extraction performance. Finally, we discuss the existing challenges and perspectives to promote the future development of the geothermal reservoir multi-field coupling model. An accurate understanding of the multi-field coupling mechanism, an efficient cross-scale modeling method, as well as the accurate characterization of reservoir fracture morphology, are crucial for the multi-field coupling model of geothermal production.@en

The effective exploitation of deep hydrothermal resource is an emphasis in the global geothermal industry. A horizontal-well coaxial closed-loop geothermal system (CCGS) is presented to realize its efficient development by significantly increasing the heat exchange area based on a long horizontal well. However, few researchers focus on the complex convection process in the hydrothermal reservoir, making it difficult to effectively evaluate the thermal characteristics of a geothermal system. Therefore, a 3D transient flow and heat transfer model considering the forced and natural convection in the reservoir is established to achieve a comprehensive CCGS analyzes. Then, the flow and temperature fields in the formation with forced and natural convection are compared. The thermal characteristics of the horizontal-well CCGS with and without convection are discussed. Also, the influences of key factors on the heat production of the horizontal-well CCGS are investigated. The differences between the horizontal-well and vertical-well CCGSs in exploiting the hydrothermal resource are analyzed. The results show that the fluid convection in the reservoir, particularly the forced convection, can greatly enhance heat transfer by affecting heat convection. The temperature field in the reservoir may return to the original state before the next heating season when a high convection velocity occurs, which is beneficial to realize 100% sustainable heat production. The horizontal length, permeability, and reverse circulation should be the primary considerations in improving heat extraction. Compared with the limited performance of vertical-well CCGS, the horizontal-well CCGS can fully extract the heat stored in the hydrothermal reservoir via a long horizontal well. The findings provide a vital reference for the CCGS scientific study and engineering application.

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Operational parameters optimization is of great significance to improve overall heat extraction performance from the hydrothermal or enhanced geothermal system. Injection flowrate, injection temperature, and production pressure are several of the easily human-controlled parameters to make the best of limited geothermal resources during the planned life. The net heat power and flow impedance are two contradictory production indexes to be optimized for efficient exploitation of long-term geothermal production. In this study, an integrated approach of finite element, multiple regression, non-dominated sorting genetic algorithm, and the technique for order preference by similarity to ideal solution is proposed and applied to the multilateral-well system to realize the optimization of geothermal development. Firstly, parametric cases coupling with thermal and hydraulic models are analyzed. Then, multiple regression is employed to obtain the net heat power and flow impedance functions considering human-controlled operational parameters and reservoir physical properties. Afterward, the multi-objective optimization algorithm is used to gain the Pareto solution set of injection and production parameters. Finally, the technique for order preference by similarity to ideal solution is employed to select the optimal combination of operational parameters for geothermal extraction. It is concluded that water loss and thermal drawdown are necessarily considered in the optimization process. The proposed approach represents global optimization. Operational parameters for the optimal case are (Q_in, T_in, p_out) which equal (49.98 °C, 62.21 kg/s, 27.44 MPa) under the conditions of this study. From the comparison between the base case and optimal case, it is observed that horizontal spread length, 2D swept area and 3D swept volume of the low-temperature scope is reduced by 77.9 m, 10 × 10⁴ m², and 16 × 10⁶ m³. Besides, the thermal breakthrough has been delayed by 1.1 years. The water loss decreases by 36.23%. The optimal case demonstrates a great improvement in production performance. Sustainable exploitation is achieved through multi-objective optimization for operational parameters. The proposed method reflects superiority, efficiency, and intelligence in geothermal development.

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