Carbon dioxide (CO₂) injection has been widely used in conventional reservoirs for enhanced oil recovery and CO₂ sequestration. Nevertheless, the effectiveness of CO₂ injection in tight reservoirs is limited due to diagenetic processes that impact displacement efficiency. This research work assesses the performance of CO₂ injection in tight reservoirs and evaluates oil mobilization and fluid distribution within the rock pore systems. A set of experiments, including routine core analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and mercury injection capillary pressure (MICP), was performed on Scioto sandstone. Three core-flooding runs were conducted to evaluate oil recovery of different injection schemes, including tertiary miscible CO₂ injection, secondary immiscible CO₂ injection, and secondary miscible CO₂ injection. A nuclear magnetic resonance (NMR) spectrometer was utilized to evaluate the fluid distribution in pre- and postflooding schemes. Results show that secondary miscible CO₂ injection provided the highest displacement efficiency (E_d) of 88%, with oil mobilized from both micro- and macropore systems, leading to the highest oil recovery of 93% original oil in place (OOIP). Tertiary miscible CO₂ injection had E_d of 67%, providing an ultimate oil recovery of 79% OOIP mostly from the macropore system. Limited contribution of micropores during the tertiary miscible CO₂ injection is attributed to the increased water content as a result of previously conducted secondary water flooding. Secondary immiscible CO₂ injection showed the least oil recovery among the injection schemes of 68% OOIP, which is attributed to the unstable displacement, as indicated by E_d of 52%. The efficiency of pore fluid displacement was determined through NMR analyses, and the findings are in line with the displacement efficiency values obtained from core-flood experiments, with a strong positive correlation. This finding is a promising strategy for determining a suitable CO₂ injection scheme in tight rocks for oil recovery and CO₂ storage.

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The microscopic structure of low-permeability tight reservoirs is complicated due to diagenetic processes that impact the pore-fluid distribution and hydraulic properties of tight rocks. As part of an ongoing study of carbon dioxide-enhanced oil and gas recovery (CO2-EOR/EGR) and CO2 sequestration, this research article adopts an integrated approach to investigate the contribution of the micropore system in pore-fluid distribution in tight sandstones. A new dimensionless number, termed the microscopic confinement index (MCI), was established to select the right candidate for microscopic CO2 injection in tight formations. Storativity and containment indices were essential for MCI estimation. A set of experiments, including routine core analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), mercury injection capillary pressure (MICP), and nuclear magnetic resonance (NMR), was performed on three tight sandstone rock samples, namely Bandera, Kentucky, and Scioto. Results indicate that the presence of fibrous illite acting as pore bridging in Bandera and Kentucky sandstone samples reduced the micropore-throat proportion (MTMR), leading to a significant drop in the micropore system confinement in Kentucky and Bandera sandstone samples of 1.03 and 0.56, respectively. Pore-filling kaolinite booklets reduced the micropore storativity index (MSI) to 0.48 in Kentucky and 0.38 in Bandera. On the other hand, the absence of fibrous illite and kaolinite booklets in Scioto sandstone led to the highest micropore system capability of 1.44 MTMR and 0.5 MSI to store and confine fluids. Therefore, Scioto sandstone is the best candidate for CO2 injection and storage among the tested samples of 0.72 MCI.@en

Macro-, meso-, micro-pore systems combined with clay content are critical for fluid flow behavior in tight sandstone formations. This study investigates the impact of clay mineralogy on pore systems in tight rocks. Three outcrop samples were selected based on their comparative petrophysical parameters (Bandera, Kentucky, and Scioto). Our experiments carried out to study the impact of clay content on micro-pore systems in tight sandstone reservoirs involve the following techniques: Routine core analysis (RCA), to estimate the main petrophysical parameters such as porosity and permeability, X-ray diffraction (XRD), and scanning electron microscopy (SEM) to assess mineralogy and elemental composition, Mercury Injection Capillary Pressure (MICP), Nuclear Magnetic Resonance (NMR), and Micro-Computed Tomography (Micro-CT) to analyze pore size distributions. Clay structure results show the presence of booklets of kaolinite and platelets to filamentous shapes of illite. The Scioto sample exhibits a micro-pore system with an average pore body size of 12.6±0.6 μm and an average pore throat size of 0.25±0.19 μm. In Bandera and Kentucky samples illite shows pore-bridging clay filling with an average mineral size of around 0.25±0.03 μm, which reduces the micro-pore throat system sizes. In addition, pore-filling kaolinite minerals with a diameter of 5.1±0.21 μm, also reduce the micro-pore body sizes. This study qualifies and quantifies the relationship of clay content with primary petrophysical properties of three tight sandstones. The results help to advance procedures for planning oil recovery and CO₂ sequestration in tight sandstone reservoirs.

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A full petrographic and petrophysical characterization of tight sandstones has been conducted as part of ongoing study of Carbon Dioxide Enhanced Oil and Gas Recovery (CO₂-EOR/EGR) and CO₂sequestration. The main purpose of this study is to give novel perception into the interplay of the rock characteristics and fluid flow in tight formations, which are candidates for EOR/EGR processes (macroscopic sweep vs. microscopic displacement efficiency). To achieve this, several experimental techniques, including routine core analysis, X-ray diffraction (XRD), X-ray fluorescence (XRF), thin sections petrography, Scanning Electron Microscopy (SEM) and capillarity/pore size distributions by using Mercury Injection Capillary Pressure (MICP), Nuclear Magnetic Resonance (NMR), and Micro-Computed Tomography (Micro-CT), were conducted. Three tight sandstone rock samples (Bandera, Kentucky, and Scioto) were used in this work and particular attention was paid to the impact of clay content on rock's pore system and other petrophysical characteristics and hence fluids flow during production process. Results indicate that the presence of fibrous illite clay acting as pore bridging in Bandera and Kentucky samples have blocked the overall micro-pore system causing a significant reduction in the micro-pore throat system to 36% in Bandera sand and 50.9% in Kentucky sample. On the other hand, absence of fibrous illite and the presence of illite platelets in the Scioto sandstone led to a clear preservation of the sample's micro-pore throat attributing to a total of 59.1% of the total pore throat system. A new dimensionless number (dimensionless micro-pore throat modality) was established, defined as the ratio of micro-to macro-pore sizes. This shows that Scioto has the highest value of 1.44 implying that both macro- and micro-pore systems contribute to flow. Therefore, the mitigation of oil bypass from smaller pores should be a key criterion in selecting the proper recovery methods. Results show the effect of clay mineralogy on pore system considering a part of the physical and spatial properties the pore/grain framework of the tight sandstones.

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