The main bottleneck of using composites for cryogenic storage of clean hydrogen fuel is the permeation of gas molecules. In this work, the permeation of hydrogen gas through thermally cycled thermoplastic composite laminates with two different stacking sequence is investigated. The experimental study is based on a methodology of cryogenically cycling the composite specimen and measuring the permeability in a dedicated hydrogen permeation setup. An optical microscope and X-ray computed tomography scanner are employed to investigate the existence of cracks. The results reveal that thermal cycling does not have a profound influence on permeability, while the stacking sequence has a considerable effect. Laminates with dispersed 0° layers resulted in lower permeation values compared to the laminate with grouped 0° layers at the laminate’s core. The imaging techniques did not reveal any observable crack which supports the hypothesis that permeation is mostly driven by bulk diffusion in the polymer. @en

Finding new ways to evaluate the variability of microstructures, and its effect on macroscopic properties such as permeability and mechanical performance [1,2] is of increasing interest in the composite field. The variability of microstructural features at a three-dimensional level is not fully understood and its effect on macroscale properties is not well established, and mostly analyzed at a phenomenological level [3]. We introduced in recent work a method based on X-ray Computed Tomography for the threedimensional reconstruction of the fibrous microstructure of unidirectional tapes at a single fibre resolution [4]. A schematic of the workflow is represented in Figure 1. Three descriptors are introduced in the work to describe increasing level of complexity in the microstructural organization, from a single fiber path level with differential tortuosity, to group behavior with collective motion, to fibre network connectivity with length of contact. These descriptors and their interdependence highlight local effects like edge-core segregation in microstructural characteristics. However, in order to achieve a more complete definition of the unidirectional tape domain, understanding of matrix-based features and its interrelation with fiber architecture descriptors is needed. In this work, we expand the methodology of Gomarasca et al. [4], to account for matrix-based phenomena such as tape boundary variability, and void formation and morphology. This will be showcased on a unidirectional composite tape including both fiber-based and matrix-based analysis. These methods enable advanced characterization and modelling of microstructural formation and evolution during composite manufacturing. @en

Understanding the three-dimensional variability of unidirectional composites is relevant to the material performance and the development of advanced material modelling strategies. This work proposes a new methodology for the characterization of unidirectional composites, showcased on carbon fibre/poly(ether-ether-ketone) tapes. Three microstructural descriptors were here introduced, each representing an increasing level of complexity in the fibre architecture: from a tortuosity-based single fibre trajectory analysis to fibre groups’ behaviour, to fibre network interconnectivity. The methodology was developed and validated on real material datasets acquired via X-ray computed tomography. A facile method for image analysis was used to reconstruct the three-dimensional fibrous architecture at a single fibre path resolution. The approach bridges a gap in the traditional approach and nomenclature typical of the composite field to describe and quantify complex fibre organization in unidirectional composites, highlighting micro- and mesoscopic features, such as edge-core effects in the fibre arrangement, possibly occurring in tow spreading. The study of the parameter interdependence showed relationships, which will provide further insight for future research in the study of microstructure formation of unidirectional composites, its evolution during processing or loading, and input for advanced modelling techniques based on Representative Volume Elements.@en

Composite materials combine the advantages of lightweight and high strength. This is in particular of interest for the development of large constructions e.g. aircraft, space applications, wind turbines etc. One of the shortcomings of using composite materials is the complex nature of the failure mechanisms which makes it difficult to predict the remaining lifetime. Therefore, condition and health monitoring are important for using composite materials for the critical parts of a construction. Different types of sensors are used to monitor composite structures. These include ultrasonic, thermography, shearography and fiber optics. Optical fiber sensors can be surface mounted or embedded in the composite construction to provide the unique advantage of in-operation measurement of mechanical strain and other parameters of interest. This is identified as a promising technology for Structural Health Monitoring (SHM) or Prognostic Health Monitoring (PHM) of composite constructions. Among the different fiber optic sensing technologies, Fiber Bragg Grating (FBG) sensors are the most mature and widely used ones. FBG sensors can be realized in an array configuration with many FBGs in a single optical fiber. In the current project, different aspects of using embedded FBG for composite wind turbine monitoring are investigated. The demonstration of using FBG sensor array for temperature and strain sensing and monitoring of a 5.8 m long scale model of a glass fiber monopile is investigated. The results indicate that the embedded FBGs successfully show the temperature increase during curing of the resin. During the static and dynamic tests, the embedded FBG sensors provided accurate monitoring.@en

The main objective of the experimental study detailed in this paper is to investigate the performance of fully recyclable, lightweight, low-cost, thermoplastic Polypropylene (PP) composite tapes at low temperatures. Coupons made of [±45] and [0/90] laminates are subjected to tensile and 3-point bending tests at room temperature as well as at −196 °C. In addition to that, cryogenic low velocity impact tests at 268 J and 777 J impact energies are performed on tubular structures. The results are indicating that the laminates made of PP tapes have sufficient ductility for cryogenic applications. Low velocity impact tests showed that the viscoelastic behavior of the material is preserved, even at such low temperatures and more than 72% of impact energy is absorbed by the material.@en

This paper reports on the cryogenic fatigue life of Al 2024 / Stycast 2850 FT composite sandwiches loaded under cyclic strain, as well as on the strength of their constituent materials at 77 K. These Fibre Metal Laminate (FML) specimen serve as a model for an alternative class of cryogenic structural materials that might be used e.g. in downstream LNG applications. FMLs, such as the GLARE ™, are already used in the aeronautic industry, where they provide better damage tolerance, corrosion resistance and lower specific weight. Their cryogenic performance, however, is yet to be understood. Preliminary results show that the metal/filled- epoxy combination presented here withstands repeated cool-down to 77 K. Moreover, its cryogenic fatigue life is at least 20 times longer than at room temperature. These observations are consistent with the measured stress-strain behaviour of the metal and the epoxy, as well as with the shear strength of the bond between them. The Youngs modulus, yield strength and tensile strength of the Stycast 2850 FT roughly double when cooled down to 77 K. In addition to this, the bond strength with the GLARE-type coated Al increases significantly. These preliminary experiments indicate that cryogenic FML are technically feasible.@en