Ce³⁺ and Eu²⁺ doped and Ce³⁺-Eu²⁺ co-doped Sr₂MgSi₂O₇ phosphors are prepared via a high-temperature solid-state reaction technique. The synchrotron radiation vacuum ultraviolet-ultraviolet (VUV-UV) excitation and ultraviolet-visible (UV-vis) emission spectra of diluted Ce³⁺ and Eu²⁺ doped Sr₂MgSi₂O₇ samples are measured at cryogenic temperatures. The electron-vibrational interaction (EVI) between Ce³⁺ and its surroundings is analyzed. The dependencies of the 4f-5d transitions of Ce³⁺ on the structure of the host compounds Sr₂MgSi₂O₇, Ba₂MgSi₂O₇ and BaMg₂Si₂O₇ are discussed in detail. Then the thermal quenching channel is proposed based on the measurements of temperature dependent luminescence intensities and decay times of Ce³⁺ and Eu²⁺ in Sr₂MgSi₂O₇, and the Ce³⁺ → Eu²⁺ energy transfer mechanism is understood by three luminescence dynamic models. In addition, Sr₂MgSi₂O₇:Ce³⁺/Eu²⁺ samples are evaluated for the possibilities of X-ray detection applications using X-ray excited luminescence (XEL) spectroscopy, and it was found that they are not suitable.

Ce3+-doped LiSr4(BO3)3 phosphors have been prepared by a high-temperature solid-state reaction method, and structural refinement of the host compound has been performed. The excitation and emission spectra in the vacuum ultraviolet-ultraviolet-visible range at cryogenic temperatures reveal that Ce3+ ions preferentially occupy eight-coordinated Sr2+ sites in LiSr4(BO3)3. Such experimental attribution is well corroborated by the calculated 4f-5d transition energies and defect formation energies of Ce3+ ions at two distinct Sr2+ sites in the first-principles framework. In addition, the doping concentration-dependent luminescence and the temperature-dependent luminescence are systematically investigated by luminescence intensity and lifetime measurements, respectively. This shows that concentration quenching does not occur in the investigated doping range, but inhomogeneous broadening exists in the concentrated samples. With the estimated thermal quenching activation energy, the discussions on the thermal quenching mechanisms suggest that the thermal-ionization process of the 5d electron is a dominant channel for thermal quenching of Ce3+ luminescence, despite the fact that thermally activated concentration quenching cannot be excluded for the highly doped samples. Finally, the X-ray excited luminescence measurement demonstrates the promising applications of the phosphors in X-ray detection.