The management of bauxite residue (BR) is a major issue for the aluminum industry because of its high alkalinity and the large volumes generated. Therefore, the recovery of rare earth elements (REEs) with or without other metals from BR and utilization of the generated residue can contribute to a solution on the management problem of BR and it can be one of the options to meet the demand of REEs. In view of the above, the selective recovery of REEs over major elements such as iron by direct acid leaching was studied initially. From the leaching results, either the recovery of REEs was low or the dissolution of iron was high. To address that, iron was removed from BR by smelting. The slag generated after smelting was leached with mineral acids. The selectivity of REEs over iron was greatly improved. However, the high level of alumina presence in BR required a large amount of fluxes thereby increasing the energy consumption in smelting. Hence, the removal (and recovery) of alumina from BR by sodium carbonate roasting was carried out. The sample, after alumina removal, was smelted and the REEs were successfully recovered from slag by leaching with mineral acids. An alternative process, called sulfation–roasting–leaching, was also developed by which the REEs can be selectively leached. The scandium recovery, however, was low. Preliminary energy and economic analysis showed that alkali roasting–smelting–leaching and sulfation–roasting–leaching were the most promising processes for the treatment of BR.@en

The dissolution of rare earth oxides in molten fluorides is a critical step in the preparation of the corresponding rare earth metals by oxide-fluoride electrolysis. However, quantitatively understanding the nature of dissolution, especially in the case of molten salts, is usually difficult to be achieved by postmortem characterization. In this paper, the dissolution behavior of Nd₂O₃ particles in molten fluorides was studied via in situ observation with confocal scanning laser microscopy. Combining direct observation with thermodynamic analyses on the oxide dissolution, the rate-limiting step(s) and the effects of parameters like temperature, salt type, and composition on the dissolution rate are identified. This study provides a methodology to estimate the dissolution kinetics of rare earth oxides in molten fluorides during their primary and secondary processing.

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