Laser-Induced Cavitation for Controlling Crystallization from Solution

Journal article (2023)

Authors

Nagaraj Nagalingam Complex Fluid Processing - Mechanical, Maritime and Materials Engineering
V.B. Korede Complex Fluid Processing - Mechanical, Maritime and Materials Engineering
C. Poelma Process and Energy
C.S. Smith ImPhys/Rieger group - AS , ImPhys/Computational Imaging - AS , Team Carlas Smith - Mechanical, Maritime and Materials Engineering , BN/Nynke Dekker Lab - AS
Remco Hartkamp Complex Fluid Processing - Mechanical, Maritime and Materials Engineering
J.T. Padding Complex Fluid Processing - Mechanical, Maritime and Materials Engineering
H.B. Eral Complex Fluid Processing - Mechanical, Maritime and Materials Engineering
Research Group
Complex Fluid Processing (Mechanical, Maritime and Materials Engineering) (TU Delft)
Copyright: © 2023 Nagaraj Nagalingam, Aswin Raghunathan, V.B. Korede, C. Poelma, C.S. Smith, Remco Hartkamp, J.T. Padding, H.B. Eral
DOI: https://doi.org/10.1103/PhysRevLett.131.124001
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Published Date

2023

Language

English

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Faculty

Mechanical, Maritime and Materials Engineering

Department

Process and Energy

Research Group

Complex Fluid Processing

Abstract

We demonstrate that a cavitation bubble initiated by a Nd:YAG laser pulse below breakdown threshold induces crystallization from supersaturated aqueous solutions with supersaturation and laser-energy-dependent nucleation kinetics. Combining high-speed video microscopy and simulations, we argue that a competition between the dissipation of absorbed laser energy as latent and sensible heat dictates the solvent evaporation rate and creates a momentary supersaturation peak at the vapor-liquid interface. The number and morphology of crystals correlate to the characteristics of the simulated supersaturation peak.

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