Microstructures in a carburized steel after isothermal pearlitic treatment

Journal article (2023)

Authors

J. Abraham Mathews Team Maria Santofimia Navarro - Mechanical, Maritime and Materials Engineering
H. Farahani Tata Steel Europe Limited, Team Maria Santofimia Navarro - Mechanical, Maritime and Materials Engineering
J. Sietsma Team Joris Dik - Mechanical, Maritime and Materials Engineering
R.H. Petrov Team Maria Santofimia Navarro - Mechanical, Maritime and Materials Engineering , Universiteit Gent
M.G. Mecozzi Team Erik Offerman - Mechanical, Maritime and Materials Engineering
Maria Jesus Santofimia Team Maria Santofimia Navarro - Mechanical, Maritime and Materials Engineering
Research Group
Team Maria Santofimia Navarro (Mechanical, Maritime and Materials Engineering) (TU Delft)
Copyright: © 2023 J. Abraham Mathews, H. Farahani, J. Sietsma, R.H. Petrov, M.G. Mecozzi, Maria Jesus Santofimia
DOI: https://doi.org/10.1016/j.jmst.2023.03.017
More Info
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Published Date

2023

Language

English

Faculty

Mechanical, Maritime and Materials Engineering

Department

Materials Science and Engineering

Research Group

Team Maria Santofimia Navarro

Abstract

The influence of carbon concentration variations on pearlite formation (20 h at 600 °C) in a case-carburized steel is investigated. The resultant microstructure shows three distinct regions: carburized case, a transition region, and the original core. The microstructural transition from the case to the core regions is observed to be relatively sharp. The investigated region of the carburized case (0.9 wt.% C) contains two types of pearlite: ferrite + cementite and ferrite + M23C6, where the pearlitic aggregate with M23C6 shows faster formation kinetics. The kinetics of pearlite formation in the transition region (0.3 wt.% C) is very slow and is observed with only M23C6 carbide. Only around 40% austenite decomposes into pearlite in the transition region, which, in comparison to the carburized case region of 0.9 wt.% C is a fraction that is lower by a factor of two. Pearlite is absent in the investigated core region (0.16 wt.% C). The microstructure in this region is predominantly martensite and pro-eutectoid ferrite, with a fraction of ferrite well below the equilibrium fraction. Ferrite formation in this region is limited by the redistribution of mainly Ni, Mn, and Cr, and their resulting solute drag effect on the austenite/ferrite interface. A thermodynamic and kinetic argumentation of these observations is provided with the help of thermodynamic data, precipitation simulations, and a general mixed-mode Gibbs energy balance model.